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A screen shot or 2 would not have conveyed the issue all that well, here's a short window capture displaying the issue (watch the address of app->vfxcfg), anyone able to understand why this difference occurs despite app pointing to the same address using the same structure as it's type?
odd_debug_issue.ogg - Google Drive
Never mind, finally found the source of the problem... I think, either way the issue no longer exists, what I fixed was the type of pointer I was using in the function (not the struct), I was still using VFXCFG** when I should've changed it to VFXCFG*, the prior was a relic from old code (had been modifying the function while I was experimenting with uniform buffers, haven't managed to use them right yet though)