ListView Items

I have a listview with a few hundred rows, and each row contains four different values that are divided by columns (looks something like this):
FileName Artist SongName Path
row1 cool.mp3 me cool C:\cool.mp3
row2 notcool.mp3 Jimbo Not Cool C:\badsongs\notcool.mp3
....
etc.

i am trying to write a playlist out of these. How can i get the information from the path column and set it as a string, or maybe each row into an array?
thanks

foreach( ListViewItem item in yourListView.Items )
{
// do whatever you want with "item" or one of it's subitems
}