Eh, GTK+ is a C library, and it is not the only GUI library out there (though you might find them all ugly, even with skinning, since that is a matter of taste). Perhaps you are thinking of Gtkmm when you say "GTK+ is for C++".GTK is ugly. GTK+ is for C++.
There are CGI libraries available for C++, though these days web development is far more common in Java, PHP and Ruby than C or C++.I can only write CGI using C, may be I will try that too for Web.
Actually, if you simply want to learn another programming language, all this talk about speed is useless, whether it be the speed of development or of program execution. Just learn the programming language you have in mind.In short all of the above and more.